Monday, April 29, 2013

Woodward ReactionWoodward cis-Hydroxylation


http://cn2013wu.wordpress.com/
The Woodward Reaction allows the synthesis of syn-diols from alkenes by the addition of iodine followed by nucleophilic displacement with acetate in the presence of water. Hydrolysis of the intermediate ester gives the desired diol.
The Prvost Reaction gives anti-diols.

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